Product ID:CERTANIUM 720, 12860
MSDS Date:01/27/1990
FSC:9150
NIIN:00N018200
MSDS Number: BLDHC

PREMIER INDUSTRIAL CORPORATION

4500 EUCLID AVENUE
CLEVELAND, OH 44103
US

Emergency Phone: 216-391-8300

Info Phone: 216-391-8300

Preparer: M B

Cage: 0EZY7

PREMIER FARNELL INDUSTRIAL CORP

CLEVELAND, OH 44103 US

Telephone: 216-391-8300

Cage: 0EZY7

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 0.1-5%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

IRON

CAS: 7439-89-6

RTECS: NO4565500

Fraction By Weight: 50-80%

CHROMIUM (SARA III)

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 1-5%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 1-5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

(ORAL,RAT) 200 MG/KG

CAS: 15096-52-3

RTECS: WA9625000

Fraction By Weight: 0.1-5%

OSHA PEL 2.5 MG(F)/M3

ACGIH TLV: 2 MG(AL)/M3

POTASSIUM TITANATE

CAS: 12030-97-6

Fraction By Weight: 1-5%

ACGIH TLV: 5 MG/M3 (MFR)

ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS

CAS: 1344-28-1

RTECS: BD1200000

Fraction By Weight: 0.1-3%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

SILICON DIOXIDE, AMORPHOUS; (SILICON DIOXIDE).

CAS: 7631-86-9

Fraction By Weight: 0.1-3%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3 TDUST

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 0.1-3%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

IF VENT IS INADEQUATE, WEAR NIOSH/MSHA

RTECS: 9999999ZZ

FROM FOOD, DRINK & ANIMAL FEEDS. IN CASE OF

RTECS: 9999999ZZ

SEE ORIGINAL MSDS FOR EXPOS LIMS APPLYING TO

RTECS: 9999999ZZ

TEMP CUTTING ENVIRONMENT.

RTECS: 9999999ZZ

MOLYBDENUM

CAS: 7439-98-7

RTECS: QA4680000

Fraction By Weight: 0.1-1%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3; 9293

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 1-5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

CALCIUM CARBONATE (MARBLE) (LIMESTONE)

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 1-15%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9192

(ORAL,RAT) 4250 MG/KG.

CAS: 7789-75-5

RTECS: EW1760000

Fraction By Weight: 1-5%

OSHA PEL 2.5 MG(F)/M3

ACGIH TLV: 2.5 MG(F)/M3

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE IRRITATION. CHRONIC:
RESPIRATORY. OVEREXP TO WELDING FUMES MAY RESULT IN DIZZINESS,
NAUSEA, OR DRYNESS OR IRRITATION OF NOSE, THROAT & EYES. CHRONIC
EXCESS WELDING FUMES ABOVE PEL OR TLV MA Y BE HAZARDOUS BECAUSE
PRLNGD & RPTD INHAL MAY BE HARMFUL TO RESP SYSTEM. SOME EXPOS/CMPDS
OF MN (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM/CR CPDS:IARC GRP 1, ACGIH GRP
1, NTP KNOWN HUMAN CARC. NI:IARC GROUP 1, NTP KNOWN ANIMAL CARC
SUSP HUMAN CARC.
Effects of Overexposure:HLTH HAZ: ARE MUTAGENIC & SUSPECTED POTENTIAL
CARCINOGENS IN EXPERIMENTAL ANIMALS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR A MINIMUM OF
15 MINUTES & CALL MD. SKIN: WASH THOROUGHLY WITH PLENTY OF WATER &
SOAP. INHAL: IF AFFECTED, REMOVE TO FRESH AIR, ADMINISTER OXYGEN &
CALL MD. INGEST: SEEK MD IMMEDIATELY, SHOW MSDS OR LABEL, INDUCE
VOMITING.

Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.

Spill Release Procedures:CONTAIN AND PICK-UP WASTE MATERIALS. PUT IN A
SEALED APPROVED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ARCS/SPARKS/FLAME MAY BE A SOURCE OF
IGNIT OF COMBUST MATLS. USE ONLY IN WELL VENT AREAS. DO NOT BREATHE
DUSTS. AVOID PRLNGD CONT W/SKIN.(SEE ING 14)
Other Precautions:KEEP OUT OF REACH OF CHILDREN. KEEP ONLY IN ORIGINAL
LABELED CONTAINERS. ALWAYS READ & FOLLOW DIRECTIONS ON PRODUCT
LABEL. ADDTNL TECHNICAL DATA SHEETS AND/OR MSDS ARE AVAIL UPON
REQUEST. FOR PROFESSI ONAL AND INDUSTRIAL USE ONLY.

Respiratory Protection:USE NIOSH/MSHA APPROVED HOOD, RESPIRATOR OR
SUPPLIED AIR MASK.
Ventilation:LOCAL: REQUIRED. MECHANICAL: REQUIRED.
Protective Gloves:WELDERS PROTECTIVE GLOVES.
Eye Protection:FACESHIELD AND COLORED ABSORPTIVE LENS.
Other Protective Equipment:WELDERS LEATHER APRON, SLEEVES AND LEGGINGS.
Work Hygienic Practices:WASH THOROUGHLY AFTER USING.
Supplemental Safety and Health
HAZ DECOMP PRODS:DEPEND ON ALLOY BEING WELDED, THE PROCESS, PROC &
ELECTRODES USED. THE CONSTITUENTS OF FUME MAY BE DIFFERENT FROM THE
INGREDS & MAY INCL PARTICLES CONTAINING IRON, MANGANESE, SILICON,
CHROMIUM, NICKEL/OTHER AMORPHOUS SLAGS. THE GASES MAY INCL CO,
OZONE, METAL OXIDES, OR METAL FLUORIDES. (SEE ING 16)

HCC:V6
Appearance and Odor:SOLID ROD.

Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:FUMES & GASES FROM WELDING & HIGH TEMP
CUTTING CANNOT BE CLASSIFIED SIMPLY. THE COMPOSITION & QTY OF BOTH
(SUPP DATA)

Waste Disposal Methods:DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.